Self-assembly of Perylene Bisimide Bridging Ligands to Zinc Phthalocyanine in Solution

Bo Gao Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237, P. R. China

Yang Li Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237, P. R. China

Jianhua Su Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237, P. R. China

He Tian Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237, P. R. ChinaCorrespondence[email protected]

Abstract

A novel supramolecular self-assembly, where a pyridyl-substituted perylene bisimide dye (DPyPBI) axially binds to zinc phthalocyanine (ZnPc), has been designed. Their coordination properties have been studied by UV/vis, fluorescence techniques and ¹H NMR spectroscopy, showing that 1:1 and 1:2 double sandwich complexes between DPyPBI and ZnPc are formed.

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Acknowledgements

This work was supported by National Science Foundation of China (90401026) and Scientific Ministry of China (2006CB806205), Scientific Committee of Shanghai.

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Self-assembly of Perylene Bisimide Bridging Ligands to Zinc Phthalocyanine in Solution

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Self-assembly of Perylene Bisimide Bridging Ligands to Zinc Phthalocyanine in Solution

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