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Supramolecular Chemistry Volume 23, 2011 - Issue 1-2: V International Symposium on Macrocyclic and Supramolecular Chemistry, Nara, Japan, 2010 – Part I
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Original Articles

Three-dimensional 3d-4f heterometallic coordination polymers: syntheses, structures and properties

Man-Sheng Chen Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructure, Nanjing University, Nanjing, 210093, P.R. China; Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, 421008, P.R. China
,
Yue Zhao Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructure, Nanjing University, Nanjing, 210093, P.R. China
,
Taka-Aki Okamura Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan
,
Zhi Su Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructure, Nanjing University, Nanjing, 210093, P.R. China
,
Wei-Yin Sun Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructure, Nanjing University, Nanjing, 210093, P.R. ChinaCorrespondence[email protected]
&
Norikazu Ueyama Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan
Pages 117-124 | Received 03 Jun 2010, Accepted 24 Jul 2010, Published online: 22 Feb 2011
 
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Abstract

Six new 3d-4f heterometallic coordination polymers, {[Ln4Cu2(INAIP)8(H2O)15]·14H2O}n [Ln = La (1), Pr (2), Nd (3)] and {[LnCo0.5(INAIP)2(H2O)2]·2H2O}n [Ln = Tb (4), Dy (5), Yb (6), H2INAIP = 5-(isonicotinamido)isophthalic acid] have been synthesised and characterised by single crystal X-ray diffraction analysis. The results of structural analyses showed that 1–3 are isomorphous showing two-fold interpenetrated three-dimensional (3D) coordination framework, while 4–6 have the same non-interpenetrated 3D structure with 2D (4, 4) lanthanide-carboxylate layers. The results revealed that the different transition metal centres have great influence on the structures of the resulted complexes in this system. In addition, thermogravimetric and magnetic properties of 1–6, and photoluminescence of 4 were investigated.

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos 20731004 and 20721002) and the National Basic Research Program of China (Grant Nos 2007CB925103 and 2010CB923303).

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