Supramolecular chemosensor for selective detection of iron in aqueous medium

Abstract

We have successfully developed a ‘turn-on’ colorimetric chemosensor for Fe³⁺ based on 1,10-phenanthroline. An amide derivative of 1,10-phenanthroline 4 was developed for the selective recognition of Fe³⁺ over Co²⁺, Cr³⁺, Cu²⁺, Mn²⁺, Ni²⁺, Ag⁺ and Zn²⁺ and could measure Fe³⁺ concentration in the range of 15–210 μM by UV–vis spectroscopy. Moreover, the addition of Fe³⁺ to a colourless solution of 4 turned its colour to light pink, indicating that 4 is capable of detecting Fe³⁺ by the naked eye. Compound 4 exhibits a major absorption band centred at 268 which shifted to 278 nm after addition of Fe³⁺, and a shoulder band around 514 nm was also observed. The complexation of Fe³⁺ with 4 was analysed at a different pH and favourable binding was observed at pH 6.2.

Keywords::

• chemosensor
• 1,10-phenanthroline
• Fe³⁺ complex

Acknowledgements

We are thankful to TUBITAK (The Scientific and Technological Research Council of Turkey) for financial support (Program #2216) and the Chemistry Department of Akdeniz University, Antalya, Turkey.