Sorption of CO₂ in a hydrogen-bonded diamondoid network of sulfonylcalix[4]areneFootnote^§
^§Dedicated to Prof. Jerry L. Atwood for 75th Birthday.

Michael A. SinnwellPhysical and Computational Science Directorate, Pacific Northwest National Laboratory, Richland, WA, USA

http://orcid.org/0000-0002-6733-8335

Jerry L. AtwoodDepartment of Chemistry, University of Missouri-Columbia, Columbia, MO, USA

http://orcid.org/0000-0002-3350-9618

Praveen K. ThallapallyPhysical and Computational Science Directorate, Pacific Northwest National Laboratory, Richland, WA, USACorrespondence[email protected]

http://orcid.org/0000-0001-7814-4467

Abstract

An organic material, p-tert-butyltetrasulfonylcalix[4]arene, self-assembles via hydrogen bonding to form a diamondoid supramolecular network. Possessing discrete, zero-dimensional (0D) microcavities, the thiacalixarene derivative adsorbs CO₂ at high pressures.

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Acknowledgments

We thank the Department of Energy, Basic Energy Sciences, Division of Materials Sciences and Engineering, under award No. KC020105-FWP12152 and PNNL, a multiprogram national laboratory operated for the U.S. Department of Energy by Battelle Memorial Institute under Contract DE-AC05-76RL01830, for support.

Notes

^§ Dedicated to Prof. Jerry L. Atwood for 75th Birthday.

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Sorption of CO₂ in a hydrogen-bonded diamondoid network of sulfonylcalix[4]areneFootnote^§
^§Dedicated to Prof. Jerry L. Atwood for 75th Birthday.

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Sorption of CO2 in a hydrogen-bonded diamondoid network of sulfonylcalix[4]areneFootnote§§Dedicated to Prof. Jerry L. Atwood for 75th Birthday.

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Sorption of CO₂ in a hydrogen-bonded diamondoid network of sulfonylcalix[4]areneFootnote^§
^§Dedicated to Prof. Jerry L. Atwood for 75th Birthday.