¹³C and Alkali NMR Studies of Electronic and Structural Properties of Alkali Fullerides

H. Alloul Physique des Solides, UA2 CNRS, Université Paris-Sud, 91405, Orsay, France; SESI, Ecole Polytechnique, 91128, Palaiseau, France

V. Brouet Physique des Solides, UA2 CNRS, Université Paris-Sud, 91405, Orsay, France

Y. Yoshinari Physique des Solides, UA2 CNRS, Université Paris-Sud, 91405, Orsay, France

L. Malier PMC, Ecole Polytechnique, 91128, Palaiseau, France

E. Lafontaine DGA-CREA, 16 bis Av. Prieur de la Cote d'Or, 94114, Arcueil, France

L. Forro Laboratoire de Physique des Solides Semicristallins, IGA, EPFL, 1015, Lausanne, Switzerland

Abstract

Extensive NMR experiments have been performed both on the ¹³C and the alkali NMR in A_nC₆₀. In the superconducting A₃C₆₀. evidences for uniaxial molecular rotations of the C₆₀ and for a low T structural anomaly will be given. The linear chain structure of A₁C₆₀ is revealed by Magic Angle Spinning NMR, while its magnetic properties are studied by ¹³C and ⁸⁷Rb wideband NMR.

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¹³C and Alkali NMR Studies of Electronic and Structural Properties of Alkali Fullerides

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¹³C and Alkali NMR Studies of Electronic and Structural Properties of Alkali Fullerides