Sensing, Threading, Orienting, and Cutting Polymers with Rigid-Rod Pores

STEFAN MATILE Department of Organic Chemistry, University of Geneva, Geneva, Switzerland

NAOMI SAKAI Department of Organic Chemistry, University of Geneva, Geneva, Switzerland

JIRI MAREDA Department of Organic Chemistry, University of Geneva, Geneva, Switzerland

JIRO KUMAKI Yashima Super-structured Helix Project, ERATO, JST Creation Core, Nagoya, Japan

EIJI YASHIMA Yashima Super-structured Helix Project, ERATO, JST Creation Core, Nagoya, Japan

Abstract

This short review describes synthetic pores that are made from rigid-rod molecules and can bind oligo-and polymers such as polyacetylenes, p-oligophenyls, terpenoids, polypeptides, polysaccharides, and oligonucleotides. The spotlight is on recent breakthroughs to image the longtime elusive pore-polymer host-guest complexes as single giant pseudorotaxanes.

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Sensing, Threading, Orienting, and Cutting Polymers with Rigid-Rod Pores

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Sensing, Threading, Orienting, and Cutting Polymers with Rigid-Rod Pores

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