ABSTRACT
The aim of this study is to assess the risk to human health presented by total chromium (CrT) and hexavalent chromium (Cr(VI)) due to the intake of the groundwater (shallow aquifer) in the Aosta Valley region. One hundred and fifty-three groundwater samples were collected from seventeen locations in the Aosta Valley region during the years 2007–2015 to determine the CrT and Cr(VI) concentrations. The cancer risk (CR) and non-cancer risk, reflected by the hazard quotient (HQ) were estimated using the United States Environmental Protection Agency methods. The concentrations of CrT exceeded the limit for drinking water established by Italian legislative decree at the sampling location Ao23 in all the years studied. Moreover, Cr(VI) concentrations exceeded the limit for drinking water at many sampling locations in the study area. The estimated HQ values for non-cancer risk suggested that all the sampling locations were well within the safe zone during all the years except for location Ao23 in many years considered. The CR levels were very low to high risk in the groundwater of the study area. The results of this analysis suggest that a suitable treatment of the groundwater is required before its utilization for drinking purposes. This study could be of great value for the prevention of risk to human health and for groundwater resource management.
Acknowledgments
The data were collected as part of a project drawn up between Politecnico di Torino and Aosta Valley regional authority. The authors are grateful to the Department of Environment & Territory and the Department of Public work, Soil Conservation & Public Housing of the Aosta Valley regional authority for their support and assistance during the field survey and for allowing publication of the data.