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Original Articles

Interference by Disodium Edetate with the Reaction of Phenylmercury Ions with Dithiocarbamate Derivatising Agents

Pages 441-449 | Published online: 23 Sep 2006
 

Abstract

The reaction of phenylmercuric nitrate with diethylamine-dithiocarbamate in the presence of disodium edetate has been investigated. Under these conditions the derivatisation reaction does not proceed cleanly but a portion of the phenylmercuric ion is converted to diphenylmercury with an equimolar amount of derivatised mercuric ion being produced. This reaction is independent of the disodium edetate concentration beyond a 1:1 mole ratio of phenylmercuric ion to edetate ion.

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