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Original Articles

Simultaneous Determination of Transition and Rare Earth Metal Ions in Nd-Fe-B Material by High Performance Ion Chromatography Using Post-Column Chelation Technique

Pages 4095-4105 | Received 03 Nov 1992, Accepted 22 Mar 1993, Published online: 23 Sep 2006
 

Abstract

The transition and lanthanide metal ions of Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu in Neodymium-iron-boron (Nd-Fe-B) magnetic material are separated and determined by high performance ion chromatography (HPIC) with spectrophotometric detection using post-column reaction methods. 4-(2-pyridylazo)resorcinol (PAR) and 2-(1,8-dihydroxy-3,6-disulfo-2-naphthylazo)benzenearsonic acid (Arsenazo-III) are used as post-column chelating agents. The reguirements for sample preparation, and characterization of the post-column reaction and the optimum conditions for the sensitive detection of these metal ions after ion chromatographic separation are discussed. The concentration of pH of the chelating medium and the composition of the eluent and the detection limits are investigated.

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