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Journal of Liquid Chromatography & Related Technologies Volume 21, 1998 - Issue 10
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Original Articles

Retention Prediction Based on the Solvatochromic Comparison Method in Reversed-Phase Capillary Electrochromatography

W. Wei Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China
,
Y. M. Wang Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China
,
G. A. Luo Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China
,
R. J. Wang Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China
,
Y. H. Guan Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China
&
C. Yan Unimicro Technologies, Inc., First Street Pleasanton, CA, 94566
Pages 1433-1443 | Received 02 Jun 1997, Accepted 18 Sep 1997, Published online: 23 Aug 2006
 
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Abstract

Retention behavior of eleven neutral compounds in reversed phase capillary electrochromatography (RP-CEC) was investigated by using solvatochromic comparison method. The retention behavior in RP-CEC can be predicted quite well based on either multiple solvatochromic parameters of solutes or solvatochromic solvent polarity measurement ET (30) of mobile phase.

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