Effect of the Chain Length and Concentration of the Alcohol Used in the Mobile Phase in Micellar Liquid Chromatography with a C₁ Column

M. C. Monge Departamento de Quimica Analitica Facultad de Ciencias, Universidad de Alcala, Alcala de Henares, Madrid, 28871, Spain

M. L. Marina Departamento de Quimica Analitica Facultad de Ciencias, Universidad de Alcala, Alcala de Henares, Madrid, 28871, Spain

J. M. Saz Departamento de Quimica Analitica Facultad de Ciencias, Universidad de Alcala, Alcala de Henares, Madrid, 28871, Spain

Abstract

The chromatographic behavior of a group of polycyclic aromatic hydrocarbons in micellar liquid chromatography with a C₁ column and hexadecyltrimethylammonium bromide and n-propanol or n-butanol as hybrid mobile phases is studied. Four equations, proposed in the literature, correlating the retention parameter (e.g., Log k' or 1/k'), surfactant concentration, and alcohol percentage were checked.

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Effect of the Chain Length and Concentration of the Alcohol Used in the Mobile Phase in Micellar Liquid Chromatography with a C₁ Column

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Effect of the Chain Length and Concentration of the Alcohol Used in the Mobile Phase in Micellar Liquid Chromatography with a C1 Column

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Effect of the Chain Length and Concentration of the Alcohol Used in the Mobile Phase in Micellar Liquid Chromatography with a C₁ Column