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Petroleum Science and Technology Volume 38, 2020 - Issue 2
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Original Articles

Core–shell structured catalyst of HZSM-5 zeolite supported on stainless steel fiber for methanol-to-aromatics

Meng ZhangEngineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, East China University of Science and Technology, Shanghai, ChinaView further author information
,
Yuehua FangEngineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, East China University of Science and Technology, Shanghai, ChinaView further author information
,
Fan YangEngineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, East China University of Science and Technology, Shanghai, ChinaView further author information
&
Xuedong ZhuEngineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, East China University of Science and Technology, Shanghai, ChinaCorrespondence[email protected]
View further author information
Pages 83-90 | Published online: 29 Oct 2019
 
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Abstract

The structured ZSM-5 zeolite supported on stainless steel fiber was developed by direct growth of zeolite on the stainless steel fiber support, and the hierarchical pores structure was prepared by employing sodium carboxymethyl cellulose as a porogen. ZSM-5/ss-fiber catalyst possessed high loading of zeolite by one-step crystallization. The samples were characterized by XRD, SEM, NH3-TPD, N2 adsorption–desorption, pyridine IR, and thermogravimetric. Corresponding catalytic performances were evaluated in methanol to aromatics. Structured ZSM-5 exhibited higher aromatics selectivities, and the structured ZSM-5 with hierarchical pores showed a longer lifetime of 168 hr, which is 2.6 times than that of unsupported ZSM-5.

Additional information

Funding

National Natural Science Foundation of China [No. 10.13039/501100001809].

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Related Research Data

Core–shell structured catalyst of HZSM-5 zeolite supported on stainless steel fiber for methanol-to-aromatics
Source: Taylor & Francis
Structure of synthetic zeolite ZSM-5
Source: Springer Science and Business Media LLC
Mechanism of Zeolite A Nanocrystal Growth from Colloids at Room Temperature
Source: American Association for the Advancement of Science (AAAS)
Synthesis of mesoporous zeolite single crystals with cheap porogens
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Overview and Industrial Assessment of Synthesis Strategies towards Zeolites with Mesopores
Source: Wiley
Synthesis and Catalytic Performances of Mesoporous Zeolites Templated by Polyvinyl Butyral Gel as the Mesopore Directing Agent
Source: American Chemical Society (ACS)
Core–shell structured catalyst of HZSM-5 zeolite supported on stainless steel fiber for methanol-to-aromatics
Source: Taylor & Francis
Mechanism of the Catalytic Conversion of Methanol to Hydrocarbons
Source: American Chemical Society (ACS)
Effect of metal on the methanol to aromatics conversion over modified ZSM-5 in the presence of carbon dioxide
Source: Royal Society of Chemistry (RSC)

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