Use of residues and by-products of the olive-oil production chain for the removal of pollutants from environmental media: A review of batch biosorption approaches

Abstract

Residues and by-products of the olive-oil production chain have been widely studied as biosorbents for the removal of various pollutants from environmental media due to their significant adsorption properties, low cost, production at local level and renewability. In this review, adsorbents developed from olive-tree cultivation residues and olive-oil extraction by-products and wastes are examined, and their sorption characteristics are described and discussed. Recent information obtained using batch sorption studies is summarized and the adsorption mechanisms involved, regarding various aquatic and soil pollutants (metal ions, dyes, radionuclides, phenolic compounds, pesticides) are presented and discussed. It is evident that several biosorbents show the potential to effectively remove a wide variety of pollutants from aqueous solutions, especially Pb and Cd. However, there is need to (a) develop standardized batch study protocols, and potentially reference materials, for effective cross-evaluation of biosorbents of similar nature and for improved understanding of mechanisms involved and (b) investigate scaling-up and regeneration issues that hold back industry-level application of preselected adsorbents.

Keywords:

• Biosorption
• Freundlich
• heavy metals
• Langmuir
• olive by-products

Funding

Ioannis Anastopoulos thanks the Greek State Scholarship Foundation (IKY) for financial support.

Appendix

Table A1. Thermodynamic parameter estimates for the biosorption of different pollutants onto various olive oil industry wastes and by-products.