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Original Articles

Relaxation of silica above and below Tg: Light scattering studies

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Pages 251-255 | Published online: 04 Aug 2009
 

Abstract

In a pure silica glass, different fictive temperatures are achieved between 1500 and 1100°C. These temperatures are checked by the position of the Si–O–Si Raman band. Light scattering for the different samples due to density fluctuations is determined by the Landau-Placzek ratio which decreases when T f decreases. Further relaxation occurs in this glass 300°C below T g; it is interpreted in correlation with the subrelaxational process induced by the diffusion of a few parts per million of impurities.

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