Influence of the short-range chemical order effect on the partial interference functions of a dilute binary liquid alloy

P. Laty Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques associé au CNRS (L.A. 29), E.X.S.E.E.G., Domaine Universitaire, B.P. No. 44, 38401, Saint Martin d'Heres, France

J. C. Joud Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques associé au CNRS (L.A. 29), E.X.S.E.E.G., Domaine Universitaire, B.P. No. 44, 38401, Saint Martin d'Heres, France

J. C. Mathieu Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques associé au CNRS (L.A. 29), E.X.S.E.E.G., Domaine Universitaire, B.P. No. 44, 38401, Saint Martin d'Heres, France

P. Desré Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques associé au CNRS (L.A. 29), E.X.S.E.E.G., Domaine Universitaire, B.P. No. 44, 38401, Saint Martin d'Heres, France

Abstract

An evaluation of the partial interference functions for a dilute binary liquid alloy in terms of the interference function of the solvent is presented. The calculation neglects size effects, but the influence of the short-range chemical order effect on the partial interference functions is studied. A quasichemical statistical treatment allows a calculation of the chemical effect to be made Results are presented for dilute alloys of Zn‒Al and Cu‒Sb and a direct comparison with experiment is made in the case of liquid Ag_0.285 Li_0.715.

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Influence of the short-range chemical order effect on the partial interference functions of a dilute binary liquid alloy

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Influence of the short-range chemical order effect on the partial interference functions of a dilute binary liquid alloy

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