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Correspondence

The influence of the substitution of 16O by 18O on the metal–insulator transition temperature of vanadium oxides and magnetite

, , &
Pages 373-376 | Received 15 Apr 1980, Accepted 30 Jul 1980, Published online: 20 Aug 2006
 

Abstract

Previous investigations of the influence of substituting 16O by 18O on the temperature of the metal–insulator transition in transition-metal oxides have been extended to V6O13, V4O7, and Fe3O4. By means of a new preparation method, which is briefly described, samples with increased content of 18O have been obtained. In all cases an increase of the transition temperature has been observed. This result is discussed with reference to recent theoretical work on the problem.

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