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Original Articles

Dodecahedral-shaped quasicrystalline precipitates in dilute Al-Mn solid solutions

, , , , &
Pages 1-13 | Received 21 Sep 1987, Accepted 26 Oct 1987, Published online: 20 Aug 2006
 

Abstract

Abstract

The Al-Mn icosahedral phase is found to precipitate and grow at room temperature from rapidly quenched Al-4 at % Mn f.c.c. solid solutions, with the composition 13•5 ± 1•5at.%Mn, the surrounding matrix having a composition of 3•1 ± 0•3 at.% Mn. Dodecahedral-shaped precipitates with orientation relationships with the f.c.c. matrix are produced. The above information is rationalized in terms of symmetry arguments and growth processes. Comparison of the compositions obtained here with that of other work extends our knowledge of the Al-Mn metastable equilibrium between the icosahedral phase and the f.c.c. Al-Mn solid solution in the solid state.

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