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Original Articles

Cyclopentadiene—iron—naphthalene tetrafluoroborate salt as a cationic photoinitiator for preparing photosensitive materials

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Pages 247-253 | Received 19 Jul 2002, Accepted 29 Jan 2003, Published online: 06 Oct 2016
 

Abstract

A novel cationic photoinitiator, cyclopentadiene-iron-naphthalene tetrafluoroborate ([Cp-Fe-Naph]BF4) salt, was synthesized, characterized and used for preparing photosensitive materials. The purification process and the reaction conditions were optimized. The highest yield can reach 82 per cent. Compared with the mono-arene iron complexes, [Cp-Fe-Naph]BF4 possesses a higher molar extinction coefficient (ε = 893 M−1 cm−1) at 373 nm in CH2C12 and is more efficient for the polymerization of epoxide when a high-pressure mercury lamp is used as an ultraviolet light source. The photosensitivity S can reach 78.1 mJ/cm2 when [Cp-Fe-Naph]BF4 is used to initiate the epoxide E44. When the photosensitizer benzoyl peroxide (BPO) is employed, [Cp-Fe-Naph]BF4 is rendered much more efficient as a photoinitiator. The best molar ratio of BPO to [Cp-Fe-Naph]BF4 is 1:1 to 1:2. In the photopolymerization of epoxide initiated by [Cp-Fe-Naph]BF4, the temperature is very important with respect to the polymerization rate. At 60°C, the polymerization can be completed in a short time.

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