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Science and Technology of Advanced Materials Volume 18, 2017 - Issue 1
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Focus on Carbon-neutral Energy Science and Technology

Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

Taisuke TokunagaInternational Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan
,
Takeshi YatabeInternational Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan
,
Takahiro MatsumotoInternational Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan
,
Tatsuya AndoInternational Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan
,
Ki-Seok YoonInternational Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan
&
Seiji OgoInternational Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, JapanCorrespondence[email protected]
Pages 870-876 | Received 17 Jun 2017, Accepted 12 Sep 2017, Published online: 01 Nov 2017
 
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Abstract

We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

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This article is part of the following collections:
Carbon-neutral Energy Science and Technology

Supplemental data

The supplemental material for this paper is available online at https://doi.org/10.1080/14686996.2017.1379857

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Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase
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