Facile synthesis of CsPbBr₃/PbSe composite clusters

Abstract

In this work, CsPbBr₃ and PbSe nanocomposites were synthesized to protect perovskite material from self-enlargement during reaction. UV absorption and photoluminescence (PL) spectra indicate that the addition of Se into CsPbBr₃ quantum dots modified the electronic structure of CsPbBr₃, increasing the band gap from 2.38 to 2.48 eV as the Cs:Se ratio increased to 1:3. Thus, the emission color of CsPbBr₃ perovskite quantum dots was modified from green to blue by increasing the Se ratio in composites. According to X-ray diffraction patterns, the structure of CsPbBr₃ quantum dots changed from cubic to orthorhombic due to the introduction of PbSe at the surface. Transmission electron microscopy and X-ray photoemission spectroscopy confirmed that the atomic distribution in CsPbBr₃/PbSe composite clusters is uniform and the composite materials were well formed. The PL intensity of a CsPbBr₃/PbSe sample with a 1:1 Cs:Se ratio maintained 50% of its initial intensity after keeping the sample for 81 h in air, while the PL intensity of CsPbBr₃ reduced to 20% of its initial intensity. Therefore, it is considered that low amounts of Se could improve the stability of CsPbBr₃ quantum dots.

Keywords:

• CsPbBr3
• PbSe
• cesium lead halide perovskite
• nanocomposite

Classification:

• 20 Organic and soft materials (colloids, liquid crystals, gel, polymers)
• 102 Porous / Nanoporous / Nanostructured materials
• 103 Composites