The synergistic action between anhydride grafted carbon fiber and intumescent flame retardant enhances flame retardancy and mechanical properties of polypropylene composites

ABSTRACT

The applications of polypropylene/carbon fiber (PP/CF) composite are hindered by the high flammability of PP substrate. This work reports a facile solvothermal method to modify CF though grafting maleic anhydride (MAH) on its surface, with the goal of enhancing the compatibility of intumescent flame retardant (IFR) with PP substrate, thus enhancing the flame-retardant and mechanical performance of the resulting PP/CF/IFR composite. The effect of maleic anhydride-g-carbon fiber (MAH-g-CF) to IFR ratio on the overall performance of the composite was assessed. The possible interactions between MAH-g-CF and IFR were characterized by dynamic thermomechanical analysis and Fourier-transform infrared spectroscopy. Results show that when 3 wt% MAH-g-CF and 22 wt% IFR were added to the PP substrate, the composite exhibited a much lower heat release rate value and smoke suppression ability. Meanwhile, the composites achieved 26.7 MPa in tensile strength and 50.6 MPa in flexural strength. We propose that MAH on MAH-g-CF acts as a compatibilizer that improves the adhesion and cross-linking between CF and IFR, thereby enhancing mechanical strength and flame-retardancy of the PP/IFR/MAH-g-CF composite.

GRAPHICAL ABSTRACT

KEYWORDS:

• Intumescent flame retardant
• carbon fiber
• polypropylene
• maleic anhydride
• grafting modification

CLASSIFICATION:

• 10 Engineering and Structural materials
• 103 Composites
• 212 Surface and interfaces
• 301 Chemical syntheses / processing

Disclosure statement

No potential conflict of interest was reported by the authors.

Supplementary material

Supplementary data can be accessed here

Additional information

Funding

The authors appreciated the financial supports from Guangdong winner High-Tec & Industry Co. Ltd. and Municipal Bureau of science and technology of Foshan, Guangdong Province, China [No.2016AG101374], National Natural Science Foundation of China [Grant No. 51572049, 51772056] and Guangxi Natural Science Foundation of China Natural Science Foundation of Guangxi Province[Grant No. 2015GXNSFFA139002].