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Energy Materials

Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications

ORCID Icon, ORCID Icon, , , , , , , & show all
Pages 735-751 | Received 21 Jul 2022, Accepted 13 Oct 2022, Published online: 07 Nov 2022
 

ABSTRACT

A wide band gap semiconductor power module can operate at higher voltages as compared with its traditional silicon counterpart. However, its insulating system undergoes stronger electric fields at the triple point between the ceramic substrate, the metallic tracks and the encapsulating polymer, which can dramatically reduce its lifespan. Here we report an original concept based on the local modification of the substrate properties to mitigate such electrical stress. Numerical simulations revealed its potential to reduce this constraint by up to 50%. This concept was realized by developing, through a practical approach, a novel substrate made of an AlN-based ceramic (material A) integrating a nanocomposite volume endowed with controlled properties and geometry. This approach implies first the spark plasma sintering of the AlN powder with additives (Y2O3, CaF2) to endow the material A with a very low electrical conductivity (σ) and high thermal conductivity (k). Graphene nanoplatelets (GNP) were incorporated within this material to fabricate a nanocomposite with a controlled σ anisotropy that otherwise reached a striking ratio of 106 at 20°C for 1.25 vol% GNP. Our approach secondly aimed at developing an effective process allowing to integrate this nanocomposite into the material A with a very high degree of reproducibility. It finally consisted in establishing the electrical contacts on the achieved substrate and encapsulating it for breakdown testing. The novel substrate enabled a mitigation of the electrical constraint by diminishing its intensity and shifting it from the triple point to a less constrained area. It already brought an improvement in breakdown voltage (VB) by 15% as compared to the traditional substrate, and revealed the potential for achieving higher VB as well. This work lays the foundation for the development of novel multifunctional ceramic-matrix composite substrates sought for power electronics as well as for other potential applications.

GRAPHICAL ABSTRACT

Acknowledgment

This work was supported by the French National Research Agency (Agence Nationale de la Recherche – ANR) through the grants ANR-16-ASTR-0009 (FILCERA Project). The authors acknowledge the French Directorate General of Armaments – DGA for funding this work and supporting it in the frame of ANR ASTRID program. They also thank Prof. Jacques NOUDEM from Normandy university for the thermal conductivity measurements, Dr. Jean Jacques DEMAI for his help in TEM observations, and Dr. Moussa GOMINA for the insightful discussions on the elaboration of ceramics.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

The work was supported by the French National Research Agency [ANR-16-ASTR-0009]