Naphthenic acid corrosion characteristic and corrosion product film resistance of carbon steel and Cr5Mo low alloy steel in secondary vacuum gas oil

Abstract

Although naphthenic acid corrosion (NAC) has been studied for many years, the mechanism of NAC is not fully understood. The objective of this paper is to study high-temperature NAC in secondary vacuum gas oil of an industrial crude oil vacuum distillation tower. A high-temperature autoclave was applied to conduct high-temperature corrosion test to investigate NAC behaviour of carbon steel and Cr5Mo low alloy steel at different sulphur contents and total acid numbers (TAN). The result shows that the corrosion rate of carbon steel and low alloy steel is high at low TAN and high TAN while it keeps at a low value at medium TAN. Corrosion product film on Cr5Mo low alloy steel surface is denser and more compact than that of carbon steel at high TAN. The chromium present in Cr5Mo low alloy steel plays an important role in NAC resistance by the formation of Cr₇S₈ film in the inner layer of the scale. Corrosion rates of the two steels in secondary vacuum gas oil are high at low TAN and high TAN, but low at medium TAN which are strange and different from previous experimental results conducted in non-industrial oil solution. A tentative explanation for this new phenomenon is also put forward.

Keywords:

• Low alloy steel
• Carbon steel
• Naphthenic Acid
• SEM
• Sulphidation
• Passive films

Acknowledgements

The author is deeply thankful to J. H. Jing, W. J. Dong, P. X. Si and H. Zeng of Jinxi Petrochemical Company, Petrochina for the assistance of experiment.

ORCID

G. Q. Liu http://orcid.org/0000-0001-8116-7651

Additional information

Funding

This work was supported by China-EU international cooperation project [SQ2013ZOG300003], Science and Technology Support Program of Ningxia province [2014ZYH50] and Major project of Beifang university of nationalities [2015KJ24].