Ultrasonic and FT-IR studies on Bi₂O₃–Er₂O₃–PbO glasses

Abstract

Glasses in the 90Bi₂O₃–(10−x)Er₂O₃−xPbO (x = 3, 5, 7, 9 and 10 mol%) system have been prepared by the melt-quenching technique. Elastic properties and FT-IR spectroscopic studies have been employed to study the role of PbO in the structure of the investigated system. Elastic properties and Debye temperature were recorded using sound wave velocity measurements at 4 MHz at room temperature. The results showed that density increased and molar volume decreased, while both sound velocities increased with an increase in x. Infrared spectra of the glasses revealed that the bismuthate network is affected by an increase in PbO content. The results are interpreted in terms of the conversion of [BiO₆] into [BiO₃] structural units, indicating that Pb ions have been substituted for erbium ions as tetrahedral network formers. The elastic moduli increased with increasing PbO content due to the increased average bond strength and degree of connectivity, as a direct effect of the increase in [BiO₃] structural units.

Keywords:

• bismuthate glasses
• ultrasonic wave velocity
• elastic moduli
• FTIR spectroscopy

Acknowledgement

The authors wish to dedicate this research paper to the memory of late Professor Dr. M.A. Sidkey of the National Institute for Standards who died during the course of this study.