Ultrasonic, FTIR and thermal investigations of SiO₂–Na₂O–CaO–P₂O₅ glasses doped with CeO₂

Abstract

The longitudinal and shear ultrasonic wave velocities for different compositions of SiO₂–Na₂O–CaO–P₂O₅ glasses were measured at room temperature (305 K) using a pulse-echo method at a frequency of 4 MHz. The elastic moduli, Poisson's ratio, microhardness, Debye temperature and other ultrasonic parameters were obtained from experimental data and analyzed using bond compression theory. By calculating the number of network bonds per unit volume, the average stretching constant, and the average ring size, information about the structure of the glass can be deduced. Structural changes after doping with CeO₂ were investigated by FTIR spectroscopy, and by measurements of the thermal expansion coefficient, glass transition and softening temperature to throw more light on the characterization of these glasses.

Keywords:

• ultrasonic velocity
• elastic moduli
• Poisson's ratio
• Debye temperature
• infrared spectra
• thermal expansion coefficient
• glass characterization