Orientation of the electric field gradient and ellipticity of the magnetic cycloid in multiferroic BiFeO₃

Abstract

The paper deals with the hyperfine interactions observed on the ⁵⁷Fe nucleus in multiferroic BiFeO₃ by means of the 14.41-keV resonant transition in ⁵⁷Fe and for transmission geometry applied to the random powder sample. Spectra were obtained at 80 K, 190 K and at room temperature. It was found that iron occurs in the high-spin trivalent state. Hyperfine magnetic field follows distribution due to the elliptic-like distortion of the magnetic cycloid. The long axis of the ellipse is oriented along 〈1 1 1〉 direction of the rhombohedral unit cell. The hyperfine magnetic field in this direction is about 1.013 of the field in the perpendicular direction at room temperature. This ratio diminishes to 1.010 at 80 K. Axially symmetric electric field gradient (EFG) on the iron atoms has the principal axis oriented in the same direction and the main component of the EFG is positive. Our results are consistent with the finding that iron magnetic moments are confined to the crystal plane.

Keywords:

• Multiferroic
• Mössbauer spectroscopy
• crystal structure
• magnetic cycloid