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Part A: Materials Science

Segregation of solute atoms in Mg–Ce binary alloy: atomic-scale novel structures observed by HAADF-STEM

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Pages 1498-1508 | Received 30 May 2016, Accepted 06 Mar 2017, Published online: 27 Mar 2017
 

Abstract

In the present study, the segregation of solute atoms from α-Mg solid solution phase in Mg–3Ce (wt.%) alloys is investigated by means of atomic-scale high angle annular dark field – scanning transmission electron microscopy. The segregation behaviours, featured by different metastable nanoscale structures, are basically categorised into two types. In type-I segregation, solute atoms occupy certain lattice sites in the α-Mg phase and form linearly outlined structures. In type-II segregation, solute Ce atoms form pure FCC structures with lattice parameters equivalent to 5.52 Å. In addition to the two types of segregation that exist in a large amount, a peculiar round-like enrichment structure of Ce is characterised, in which Ce-enriched clusters align along Mg and Mg directions and form the round-like shape when viewed as a whole.

Acknowledgements

The authors extend their gratitude to Yunwen Chen (Zhejiang University), Laijin Luo (Shenzhen Foreign Languages School), Haiyan Wang, Zhihua Zheng, Xiangzhong Ren (Shenzhen University) and Chengli Wang.

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