Investigation of 1,3-Dipolar Cycloaddition Reactions of Unsaturated Nitrones in Ionic Liquids

M. Hornyák Department of Medicinal Chemistry, University of Szeged, Szeged, Hungary

Z. Kele Department of Medicinal Chemistry, University of Szeged, Szeged, Hungary

L. Kovács Department of Medicinal Chemistry, University of Szeged, Szeged, Hungary

P. Forgó Department of Organic Chemistry, University of Szeged, Szeged, Hungary

N. M. Howarth Department of Chemistry, Heriot-Watt University, Edinburgh, Riccarton, U.K.

Abstract

The effect of the media (achiral and chiral ionic liquids) on the stereochemistry of intramolecular 1,3-dipolar cycloaddition reactions of D-galactose-derived ω-unsaturated nitrones, leading to bicyclic isoxazolidines, has been investigated.

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Presented at the XVI International Roundtable Conference, September 12–16, 2004.The financial support of the Wellcome Trust (grant no. 063879/Z/01/Z) and EU FP6 grant (TRIoH LSHB-CT-2003-503480) is gratefully acknowledged

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Investigation of 1,3-Dipolar Cycloaddition Reactions of Unsaturated Nitrones in Ionic Liquids

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Investigation of 1,3-Dipolar Cycloaddition Reactions of Unsaturated Nitrones in Ionic Liquids

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