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2-Amino-α-D-ribofurano[1′,2′:4,5]-2-oxazoline reacted with α-bromoacrylonitrile yielding 2,2′-anhydro-1-α-D-ribofuranosylcytosine which was converted to α-cytidine and α-2′-deoxycytidine. Reaction of 2-amino-α-D-ribofurano[1′,2′:4,5]-2-oxazoline and ethyl α-(bromomethyl)acrylate afforded 2,2′-anhydro-1-α-D-ribofuranosylthymine, a precursor of α-thymidine and α-ribothymidine.
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