Oxidation-Reduction Sequence for the Synthesis of Peracylated Fluorodeoxy Pentofuranosides

Igor A. Mikhailopulo Institute of Bioorganic Chemistry, Byelorussian Academy of Sciences, 220141, Minsk, Zhodinskaya, 5/2, Byelorussia

Nicolai E. Poopeiko Institute of Bioorganic Chemistry, Byelorussian Academy of Sciences, 220141, Minsk, Zhodinskaya, 5/2, Byelorussia

Grigorii G. Sivets Institute of Bioorganic Chemistry, Byelorussian Academy of Sciences, 220141, Minsk, Zhodinskaya, 5/2, Byelorussia

Natalia B. Khripach Institute of Bioorganic Chemistry, Byelorussian Academy of Sciences, 220141, Minsk, Zhodinskaya, 5/2, Byelorussia

Abstract

Oxidation of 1a with DMSO-acetic or trifluoroacetic anhydride led to the formation of a mixture of epimeric gem-diols 2 and 3 in the ratios of ≍3:1 and ≍7:1, respectively. Reduction of this mixture with NaBH₄ followed by benzoylation and chromatography afforded 4a and 5a.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Oxidation-Reduction Sequence for the Synthesis of Peracylated Fluorodeoxy Pentofuranosides

Information for

Open access

Opportunities

Help and information

Oxidation-Reduction Sequence for the Synthesis of Peracylated Fluorodeoxy Pentofuranosides

Abstract

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature