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Original Articles

The Kinetics of Lipophilic Amine Addition to Fullerene C60

, , , , &
Pages 315-319 | Published online: 22 Aug 2006
 

Abstract

The reaction rate between hexadecylamine with fullerene is measured by a simple method for different temperatures and mole ratios of hexadecylamine to C60. Zero-order rate law can be assumed for the product formation in this reaction. The mole ratio of the amine:fullerene is optimized in terms of the conversion rate of C60. The reaction rate is slower than that expected for a simple collision between C60 and the amine. Temperature dependence of the reaction rate is determined and the activation energy is also estimated.

Acknowledgment

The work is fully supported by RIPI at National Iranian Oil Company.

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