Hierarchy of Structural Organization of Fullerene‐Containing Polyvinylformamide in Solutions

V. T. Lebedev Petersburg Nuclear Physics Institute RAS, St. Petersburg, RussiaCorrespondence[email protected]

Gy. Torok Research Institute for Solid State Physics & Optics, Budapest, Konkoly‐Thege, Hungary

O. V. Nazarova Institute of Macromolecular Compounds RAS, St. Petersburg, Russia

E. F. Panarin Institute of Macromolecular Compounds RAS, St. Petersburg, Russia

D. N. Orlova Petersburg Nuclear Physics Institute RAS, St. Petersburg, Russia

G. M. Pavlov Institute of Physics, St. Petersburg State University, St. Petersburg, Russia

Abstract

Structural peculiarities star‐shape polyvinylformamide (PVF) grafted to C₆₀ have been studied by small‐angle neutron scattering in heavy water at 20°C in the range of neutron momentum transfer q=0.03–4 nm⁻¹ to cover spatial scales from monomer unit (fullerene) size up to star diameter and clusters dimension. In stars (functionality f∼4) the arms take a very strained conformation regarding to free chains in solution that induces molecular assembly.

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Hierarchy of Structural Organization of Fullerene‐Containing Polyvinylformamide in Solutions

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Hierarchy of Structural Organization of Fullerene‐Containing Polyvinylformamide in Solutions

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