Photochemical Reaction of Furans in the Presence of [60] Fullerene

Yusuke Tajima Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, l-3 Kagurazaka, Shinjuku-ku, Tokyo, 162, Japan; The Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama, 351-01, Japan

Hisayoshi Arai Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, l-3 Kagurazaka, Shinjuku-ku, Tokyo, 162, Japan

Yoshihiko Tezuka Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, l-3 Kagurazaka, Shinjuku-ku, Tokyo, 162, Japan

Tadahiro Ishii Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, l-3 Kagurazaka, Shinjuku-ku, Tokyo, 162, Japan

Kazuo Takeuchi The Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama, 351-01, Japan

Abstract

The first evidence was presented which supports a photochemical pathway during the reaction of furan derivatives in the presence of C₆₀, which was formerly believed to proceed via a thermal [2+4]-concerted cycloaddition reaction of furans with C₆₀. LD-TOF-MS, UV-vis, FT-IR and ¹H-, ¹³C-NMR spectra showed that

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Photochemical Reaction of Furans in the Presence of [60] Fullerene

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