Microwave rapid synthesis of CuxO@polypyrrole nanofibre (PpyNF) composites for supercapacitors

Abstract

CuxO@polypyrrole nanofibre (PpyNF) composites were synthesized by a simple and fast microwave method. The samples were characterized using X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy; galvanostatic charge–discharge tests, cyclic voltammetry and electrochemical impedance spectroscopy were also conducted. The PpyNF composites showed a maximum specific capacitance of 464.6 F g⁻¹ at 0.5 A g⁻¹ with excellent cyclability (95.6% capacitance retention after 2,000 cycles at 1 A g⁻¹), thereby demonstrating their excellent potential for application to supercapacitors. An asymmetric supercapacitor based on CuxO@PpyNF//active carbon revealed a maximum gravimetric energy density of 12.50 Wh kg⁻¹ and power density of 0.38 kW kg ⁻¹.

Keywords:

• Polypyrrole nanofibre
• CuxO
• microwave
• supercapacitor