Fullerenes in Chinese Ink Sticks (“Sumi”)

Abstract

Small amounts (up to 0.1%) of C₆₀ and C₇₀ have been detected by high-pressure liquid chromatographic (HPLC) analysis of toluene extracts from soots used to manufacture Chinese ink sticks, or Sumi. These soots have been prepared by slow burning of pine wood, and later various seed oils. Turpentine oil, the major constituent of pine wood oil, have been found to produce twice as much fullerenes as does toluene when used as the combustion material. The yields of fullerene from unsaturated combustion materials decrease with the iodine number, reaching zero in the saturated compounds. Possible role of fullerenes as the effective gloss enhancer for black color is suggested in reference to the known technique of adding a natural red pigment to Sumi practiced in Japan.