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Research Article

Diamond-based nanostructures with metal-organic molecules

ORCID Icon, , ORCID Icon, , , , , & ORCID Icon show all
Pages S34-S43 | Received 16 Jun 2021, Accepted 08 Oct 2021, Published online: 22 Oct 2021
 
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ABSTRACT

Recent results on synthesis, structural, and physicochemical studies of complexes based on detonation nanodiamonds modified with metal-organic molecules with functional magnetic and fluorescent properties have been presented. Neutron scattering experiments have discovered subtle features of the assembly of electro-negative molecules of Eu diphthalocyanines and nanodiamonds with positive surface potential in aqueous media. Nanoscale ordering of diamonds reinforced by their linking via diphthalocyanines was confirmed by TEM. The stable complexes possess X-ray luminescent and magnetic properties. Such nanostructures with low toxicity are prospective as contrasting and photoactive agents for magnetic resonance imaging and photodynamic therapy.

Acknowledgments

The work was supported by the Russian Foundation for Basic Researches under Grant no. 18-29-19008. The authors are grateful for TEM measurements carried out at the Interdisciplinary Resource Center for Nanotechnology, St. Petersburg State University Science Park.

Disclosure Statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the the Russian Foundation for Basic Research (RFBR) [18-29-19008].

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