Photochromism of Diarylethene Zinc Complexes

Kenji Matsuda Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, and PRESTO, JST, Fukuoka, JapanCorrespondence[email protected]

Kohsuke Takayama Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, and PRESTO, JST, Fukuoka, Japan

Yoshihiro Shinkai Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, and PRESTO, JST, Fukuoka, Japan

Masahiro Irie Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, and PRESTO, JST, Fukuoka, Japan

ABSTRACT

Zinc complexes composed of bidentate 1,2-bis(2-methyl-5-(4-pyridyl)-3-thienyl)perfluorocyclopentene ( 1a ) or monodentate 1-(2-methyl-5-phenyl-3-thienyl)-2-(2-methyl-5-(4-pyridyl)-3-thienyl) perfluorocyclopentene ( 2a ) photochromic ligands and Zn(hfac)₂ or ZnCl₂ were prepared and their photochromic properties were studied.

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Acknowledgments

This work was partly supported by PRESTO of Japan Science and Technology Corporation (JST).

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Photochromism of Diarylethene Zinc Complexes

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Photochromism of Diarylethene Zinc Complexes

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