Influence of Hexacatenar Structure on Supramolecular Organization in CT-Complexes With TNF and (−)-TAPA

G. F. Gabdulsadykova Ivanovo State University, Nanomaterials Research Institute, Ermak Str. 39, 153025, Ivanovo, Russia; Ivanovo State Medical Academy, F. Engels Av. 8, 153012, Ivanovo, Russia

M. A. Zharova Ivanovo State University, Nanomaterials Research Institute, Ermak Str. 39, 153025, Ivanovo, Russia

N. V. Usol’tseva Ivanovo State University, Nanomaterials Research Institute, Ermak Str. 39, 153025, Ivanovo, Russia

V. V. Sotsky Ivanovo State University, Nanomaterials Research Institute, Ermak Str. 39, 153025, Ivanovo, Russia

A. V. Kazak Ivanovo State University, Nanomaterials Research Institute, Ermak Str. 39, 153025, Ivanovo, Russia

Abstract

Numerical experiments to obtain theoretical data on the charge transfer complex structure, formed by the substituted benzylamine derivatives (hexacatenars) and electron acceptors—TNF or (−)-TAPA, have been performed. It is shown that the configuration and extent of the central fragment of the hexacatenar molecules influence the supramolecular organization in the modeling CT-complexes.

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Acknowledgment

This work was supported by the FTP grant No 16.740.11.0206.

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Influence of Hexacatenar Structure on Supramolecular Organization in CT-Complexes With TNF and (−)-TAPA

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Influence of Hexacatenar Structure on Supramolecular Organization in CT-Complexes With TNF and (−)-TAPA

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