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Liquid Crystals

Polystyrene Blend Alignment Layers for Pretilt Angle Control of Liquid Crystal

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Abstract

We prepared blend alignment layer based on polystyrene containing 7-hydroxycoumarin (P7COU) and polystyrene containing 2-naphthoxy (P2NAP) side groups for liquid crystal (LC) alignment. The LC cells made from the rubbed P7COU/P2NAP blended films exhibited a shift of the LC alignment direction by approximately 20° compared with those made from a polystyrene film. Stable and homogeneous planar LC cells having pretilt angles adjustable from 0° to 5° were obtained from these polymer films having molar contents of P7COU and P2NAP in the ranges of 100–80 and 0–20 mole%, respectively. The LC alignment behavior was well correlated with the wettability of the polymer films.

Acknowledgments

Financial support by the Samsung Electronics Co. Ltd. and Soongsil University is gratefully acknowledged. Authors express their gratitude to Prof. J.-C. Lee at Seoul National University for useful discussions.

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