Advanced nanostructure Ti_0.7In_0.3O₂ support enhances electron transfer to Pt: Used as high performance catalyst for oxygen reduction reaction

ABSTRACT

The slow rate of the oxygen reduction reaction (ORR) and the instability of Pt based catalysts are two of the most important issues which must be solved in order to make proton exchange membrane fuel cells (PEMFCs) a reality. Here, we present a new approach by exploring robust non-carbon Ti_0.7In_0.3O₂ used as a novel functionalised co-catalytic support for Pt. This approach is based on the novel nanostructure Ti_0.7In_0.3O₂ support with “electronic transfer mechanism” from Ti_0.7In_0.3O₂ to Pt that can modify surface electronic structure of Pt, owing to a shift in the d-band centre of the surface Pt atoms. The 20 wt% Pt/Ti_0.7In_0.3O₂ catalyst shows high activity than that of that of the commercial 20 wt% Pt/C (E-TEK). Our data suggest this enhancement is a result of both the electronic structure change of Pt upon its synergistic interaction with Ti_0.7In_0.3O₂ and the inherent structural and chemical stability and the corrosion-resistance of the Ti_0.7In_0.3O₂ in acidic and oxidative environments.

KEYWORDS:

• ORR
• Ti_0.7In_0.3O₂
• PEMFC
• support
• catalyst

Acknowledgments

We are grateful for finacial support from the National Foundation for Science and Technology Development (NAFOSTED) given under a special program for Basic Research Projects in Natural Science 2014 (Grants No. 104.03-2014.92) and Dr. Bach Long Giang, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam supported for this work.