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Molecular Crystals and Liquid Crystals Volume 664, 2018 - Issue 1
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Low-Dimensional Solids and Molecular Crystals

Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine

Hui LiDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaCorrespondence[email protected]
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Chen-Zhong YaoDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Xiao-Chuan ChaiDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Gao-Feng WangDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Jun LiDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Jie WangDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Zhuang-Wei WeiDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Fu-Lin ZhouDepartment of Applied Chemistry, Yuncheng University, Yuncheng, ChinaView further author information
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Pages 156-164 | Published online: 21 Jun 2018
 
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ABSTRACT

Two monosubstituted diiron complexes, namely (µ-SCH2CH2CH2S-µ)Fe2(CO)5L (L = P(2-C4H3O)3, 2; Ph2PCH2CH2CH3, 3), have been prepared by the carbonyl substitution of the parent complex (µ-SCH2CH2CH2S-µ)Fe2(CO)6 (1) with the corresponding monophosphine ligands in the presence of Me3NO·2H2O. The new complexes were characterized by elemental analysis, spectroscopy and single crystal X-ray diffraction analysis.

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Funding

The authors gratefully acknowledge the support of the Natural Science Foundation of China (Grant no. 21576230).

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Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine
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Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine
Source: Taylor & Francis

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