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Research Article

Conjugated polymer electrolyte with nitrosonium tetrafluoroborate as the interlayer for polymer solar cells

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Abstract

High-performance devices can be achieved by lowering the work function of the cathode electrode. Herein, we synthesized polyelectrolyte that has functionality at the side chain, named PFB. In addition, a p-type dopant, NOBF4 (nitrosonium tetrafluoroborate), was used to enhance the performance of the polyelectrolyte. This polyelectrolyte was adapted as an interlayer to improve the performances of polymer solar cells (PSCs). The PSCs based on PFB and NOBF4-PFB demonstrate higher power conversion efficiency (PCE) of 9.41% and 9.51% than pristine PSC using PTB7-Th as a reference (8.7%).

Additional information

Funding

This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20194010201840) and was supported by the BB21+ Project in 2019.

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