A NEW ANISOTROPIC CONDUCTOR BASED ON IRIDIUM COMPLEXES OF TETRACYANOBIIMIDAZOLE

P. G. Rasmussen Dept. Chem., Univ. Mich., Ann Arbor, MI, 48109, U.S.A.

O. H. Bailey Dept. Chem., Univ. Mich., Ann Arbor, MI, 48109, U.S.A.

J. E. Anderson Dept. Chem., Univ. Mich., Ann Arbor, MI, 48109, U.S.A.

J. B Kolowich Dept. Chem., Univ. Mich., Ann Arbor, MI, 48109, U.S.A.

J. C. Bayon Dept. Chem., Univ. Mich., Ann Arbor, MI, 48109, U.S.A.

Abstract

A new anisotropically conductive system is reported based on the partial oxidation of the anion [Ir(CO)₂Tcbiim]⁻. Both counter cation and anion are found in the neutral stack. The structure of an Ir(II) precursor is related to the conductive system. (H₂Tcbiim = 4, 4′, 5, 5′ tetracyano-2, 2′-biimidazole.)

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A NEW ANISOTROPIC CONDUCTOR BASED ON IRIDIUM COMPLEXES OF TETRACYANOBIIMIDAZOLE

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A NEW ANISOTROPIC CONDUCTOR BASED ON IRIDIUM COMPLEXES OF TETRACYANOBIIMIDAZOLE

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