ABSTRACT
Nanoporous carbon is coated by pure nickel via an electroless plating method. The nanoporous carbon provides a high-surface-area substrate, leading to a large capacitance; the nickel surface layer is of a high work function, resulting in a thermally sensitive electrode potential. Such a system is ideal for thermally chargeable supercapacitor (TCS) system, which converts low-grade heat (LGH) to electrical energy. The specific energy per thermal cycle per gram of electrode mass is ~1.8 mJ, with a temperature difference of 50°C.
Funding
The experimental research was supported by the National Science Foundation under Grant No. ECCS-1028010. The data analysis was supported by the Advanced Research Projects Agency–Energy under Grant No. DE-AR0000396.