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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 36, 2006 - Issue 5
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Original Articles

Synthesis, Characterization and X‐ray Crystal Structures of New Ethylxanthato Complexes of Zinc(II) with N‐donor Ligands

Irene Ara Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza‐CSIC, Zaragoza, SpainCorrespondence[email protected]
,
Fatima El Bahij Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza‐CSIC, Zaragoza, Spain
&
Mohamed Lachkar Département de Chimie, Faculté des Sciences Dhar‐Mehraz, Université Sidi Mohamed Ben Abdellah, Fes, Morocco
Pages 399-406 | Accepted 29 Mar 2006, Published online: 15 Feb 2007
 
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Abstract

Zn(II) complexes of general formula [Zn(S2COEt)2L] [L=pyrazole (Hpz) 1; 3,5‐dimethylpyrazole (Hdmpz) 2; 2‐pyridylamine (pyam) 3; phenyl 2‐pyridylamine (phpyam) 4; 2,2′‐dipyridylamine (dpyam) 5; 1,4‐pyrazine (pyr) 6] have been synthesized and characterized by elemental analyses and IR and NMR spectroscopy. The crystal structures of complexes 2, 5 and 6 have been determined by X‐ray diffraction, showing different geometries and modes of coordination of the xanthate ligand depending on the type of N‐donor ligand.

We thank the Ministerio de Ciencia y Tecnología and FEDER (Project BQU2002‐03997‐CO2‐02) and Diputación General de Aragón (Spain) for their support of this research.

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