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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 36, 2006 - Issue 7
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Original Articles

Solvent‐Free Oxidation of Secondary Alcohols with Chromium Trioxide

Ji‐Dong Lou College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, ChinaCorrespondence[email protected]
,
Long‐Hua Zhu College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, China
,
Li‐Li Pan College of Biology and Environment Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang, China
,
Li Li Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Oeiras, Portugal
,
Feng Li Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Oeiras, Portugal
&
Chun‐Ling Gao Center for Prostate Disease Research, Uniformed Service University of Health Science, Bethesda, Maryland, USA
Pages 585-587 | Received 25 May 2006, Accepted 03 Jun 2006, Published online: 15 Feb 2007
 
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Abstract

Efficient oxidation of secondary alcohols into the corresponding ketones with chromium trioxide at room temperature under solvent‐free condition is described. This oxidation is generally applicable to a range of secondary alcohols especially including some quite sensitive functionalized alcohols, and gives the corresponding ketones in 85–97% yields.

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