The synthesis, crystal structure and magnetic properties of a novel diamagnetic metal complex with thiazole‐substituted nitronyl nitroxide radicals, [Ag (NIT2‐thz)2](NO3) (NIT2‐thz=2‐(2′‐thiazole)‐4,4,5,5‐tetramethylimidazoline‐1‐oxyl‐3‐oxide), is reported. The structure of the complex consists of tetracoordinated [Ag (NIT2‐thz)2]+ cations and uncoordinated nitrate anions. The radical behaves as a bidentate chelating ligand through one nitronyl nitroxide oxygen and the thiazole nitrogen. Magnetic susceptibility data showed that there are weak intramolecular anti‐ferromagnetic interactions between the radicals in the complex.
![Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days]({"type":"image" , "src" : "/sda/110819/TOC-Subject-Sample-2021-Physical-Sciences.jpg"})
Reprints and Corporate Permissions
Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?
To request a reprint or corporate permissions for this article, please click on the relevant link below:
Academic Permissions
Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?
Obtain permissions instantly via Rightslink by clicking on the button below:
If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.
Related Research Data
CCDC 204119: Experimental Crystal Structure Determination
Source:
Cambridge Crystallographic Data Centre
Linking provided by
