Synthesis, Crystal Structure and Properties of a Novel Cu(II) Complex with α‐Furan Carboxylate, [Cu(fura)₂(bpy)(H₂O)], (fura=α‐Furan Carboxylate, bpy=2,2′‐bispyridine)

Xian‐Fu Zheng College of Science, Henan Agricultural University, Zhengzhou, P. R. China

Ying‐Xia Zhou College of Science, Henan Agricultural University, Zhengzhou, P. R. China; Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Hong‐Yun Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. ChinaCorrespondence[email protected]

Xiao‐Qing Shen Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Yun‐Yin Niu Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Cao‐Yuan Niu College of Science, Henan Agricultural University, Zhengzhou, P. R. China; Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Ben‐Lai Wu Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

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A novel Cu (II) complex with α‐furan carboxylate and 2,2′‐bispyridine, [Cu(fura)₂(bpy)(H₂O)], is synthesized. Its crystal structure is determined by X‐ray diffraction analysis, and it belongs to the monoclinic system and space group P2(1)/c with CuO₃N₂ architecture. The crystal structural unit constructs distorted quadrangle pyramid geometry. The fluorescent and thermal properties of the complex were also studied.

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We gratefully acknowledge financial support from the Natural Science Foundation of China (20671083) and the Science and Technology Foundation of Henan Province (0524270061).

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Synthesis, Crystal Structure and Properties of a Novel Cu(II) Complex with α‐Furan Carboxylate, [Cu(fura)₂(bpy)(H₂O)], (fura=α‐Furan Carboxylate, bpy=2,2′‐bispyridine)

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Synthesis, Crystal Structure and Properties of a Novel Cu(II) Complex with α‐Furan Carboxylate, [Cu(fura)2(bpy)(H2O)], (fura=α‐Furan Carboxylate, bpy=2,2′‐bispyridine)

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Synthesis, Crystal Structure and Properties of a Novel Cu(II) Complex with α‐Furan Carboxylate, [Cu(fura)₂(bpy)(H₂O)], (fura=α‐Furan Carboxylate, bpy=2,2′‐bispyridine)