Synthesis, Crystal Structure and Properties of the Enantiotopic Complex Constructed From Chiral Ligand H₂bpb, [Co(H₂bpb)₂(NCS)₂(CH₃OH)₂] (H₂bpb=1,2‐Bis(3‐pyridylcarboxamide)benzene)

Ping Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Ben‐Lai Wu Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Yun‐Yin Niu Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Hong‐Yun Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. ChinaCorrespondence[email protected]

Cao‐Yuan Niu Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

Hong‐Wei Hou Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China

A six‐coordinating cobalt () complex, [Co(H₂bpb)₂(NCS)₂(CH₃OH)₂], where H₂bpb is 1,2‐bis(3‐pyridylcarboxamide)benzene, was prepared and characterized by IR spectrum and thermal analysis, its crystal structure was determined X‐ray analysis. It crystallizes in the triclinic system with space group P‐1 with a=8.7005(9) Å, b=9.6114(10) Å, c=13.767(2) Å, α= 101.393(2)^o, β=93.185(2)^o, γ=114.5180(10)^o, V=1014.5(2) Å, Z=1. Fluorescent and thermal properties of the complex were also investigated.

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We gratefully acknowledge financial support from the National Natural Science Foundation of China (20671083) and the Science and Technology Foundation of Henan Province (0524270061).

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Synthesis, Crystal Structure and Properties of the Enantiotopic Complex Constructed From Chiral Ligand H₂bpb, [Co(H₂bpb)₂(NCS)₂(CH₃OH)₂] (H₂bpb=1,2‐Bis(3‐pyridylcarboxamide)benzene)

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Synthesis, Crystal Structure and Properties of the Enantiotopic Complex Constructed From Chiral Ligand H2bpb, [Co(H2bpb)2(NCS)2(CH3OH)2] (H2bpb=1,2‐Bis(3‐pyridylcarboxamide)benzene)

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Synthesis, Crystal Structure and Properties of the Enantiotopic Complex Constructed From Chiral Ligand H₂bpb, [Co(H₂bpb)₂(NCS)₂(CH₃OH)₂] (H₂bpb=1,2‐Bis(3‐pyridylcarboxamide)benzene)