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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 42, 2012 - Issue 1
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Original Articles

A Linear Piperazine-Containing Ligand and Its Hg Coordination Polymer

Wen-Juan Chu Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
,
Rui-Jun Li Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
,
Yao-Ting Fan Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
&
Hong-Wei Hou Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
Pages 9-13 | Received 10 May 2011, Accepted 04 Jun 2011, Published online: 31 Jan 2012
 
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Abstract

Reactions of piperazine hexahydrate with triazol and paraformaldehyde afford a new piperazine-containing ligand: (N,N′-bis(1-H-1,2,4-triazole-1-yl)piperazine) (btp). X-ray crystal diffraction reveals that btp is an overall linear structure. Its Hg2+ polymer displays a zigzag chain in which piperazine is held in the chair conformation. In addition, the spectra properties of the btp and 1 are investigated, the strong luminescence characteristics of btp and 1 are found.

Acknowledgments

The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (No. 20871106 and 90610001).

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